Chlorine vs Bromine

Chlorine and Bromine sit in the same column of the periodic table — same family, one period apart — so almost every difference between them comes from one thing: the extra electron shell Bromine wears.

Side by side

PropertyChlorineBromine
SymbolClBr
Atomic number (Z)1735
Atomic mass35.45 u79.904 u
CategoryHalogenHalogen
Group1717
Period34
Phase at room tempgasliquid
Electron configuration[Ne] 3s^2 3p^5[Ar] 3d^10 4s^2 4p^5
Valence electrons77
Atomic radius79 pm94 pm
Electronegativity3.162.96
First ionisation energy1251 kJ/mol1140 kJ/mol

The verdicts

  • Bigger atom: Bromine — the lower an element sits in its group, the more shells it wears.
  • Greedy electron-taker: Chlorine — higher electronegativity means it pulls shared electrons harder.
  • Heavier: Bromine — compare the atomic masses in the table above.

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