Fluorine vs Chlorine

Fluorine and Chlorine sit in the same column of the periodic table — same family, one period apart — so almost every difference between them comes from one thing: the extra electron shell Chlorine wears.

Side by side

PropertyFluorineChlorine
SymbolFCl
Atomic number (Z)917
Atomic mass18.998 u35.45 u
CategoryHalogenHalogen
Group1717
Period23
Phase at room tempgasgas
Electron configuration[He] 2s^2 2p^5[Ne] 3s^2 3p^5
Valence electrons77
Atomic radius42 pm79 pm
Electronegativity3.983.16
First ionisation energy1681 kJ/mol1251 kJ/mol

The verdicts

  • Bigger atom: Chlorine — the lower an element sits in its group, the more shells it wears.
  • Greedy electron-taker: Fluorine — higher electronegativity means it pulls shared electrons harder.
  • Heavier: Chlorine — compare the atomic masses in the table above.

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