104RfRutherfordium[267]
A real sample of the element Rutherfordium
Synthetic element — no real sample has ever been photographed
Transition metal

Rutherfordium (Rf)

“Born into a thirty-year Cold War feud: the Soviets called it kurchatovium, the Americans rutherfordium, and IUPAC only ruled in 1997.”

Atomic number104
Atomic mass[267]
Group4
Period7
BlockD-block
PhaseSolid
Electron structure

How its electrons are arranged

Rf
[Rn] 5f14 6d2 7s2
Shell 1
2e⁻
Shell 2
8e⁻
Shell 3
18e⁻
Shell 4
32e⁻
Shell 5
32e⁻
Shell 6
10e⁻
Shell 7
2e⁻

Computed from the aufbau principle, with known real-world exceptions applied automatically.

Study

The notes

About the element

Characteristics

  • The first transactinide element: a synthetic, fiercely radioactive transition metal opening Period 7’s d-block in Group 4, below titanium, zirconium and hafnium.
  • Its chemistry, studied atom by atom, confirms it behaves like a very heavy hafnium — forming volatile RfCl4\mathrm{RfCl_{4}} and complex ions in solution.
  • The longest-lived isotope Rf-267 survives about an hour; most other isotopes decay within seconds.
  • Relativistic effects tweak its electron orbitals slightly, so it is not a perfect hafnium copy — precisely what chemists are eager to probe.
Appearance

Nobody has ever collected enough rutherfordium to see it — experiments work with single atoms. It is predicted to be a dense, hard, silvery transition metal resembling its Group 4 partners zirconium and hafnium, though bent by strong relativistic effects.

Real world

Where you meet it

✦ Uses

  • Testing the limits of the periodic law: single-atom rutherfordium chemistry checks whether group relationships survive in superheavy atoms.
  • Benchmarking gas-phase and aqueous separation methods for everything beyond Z = 104 — techniques proven on Rf are reused for Sg, Bh and Hs.
  • Nuclear spectroscopy: the alpha-decay chains of its isotopes help map the approach toward the predicted island of stability.

◍ Everyday examples

  • Every NCTB science student meets Rutherford through the gold-foil alpha-scattering experiment — element 104 carries that name forward.
  • The rutherfordium-versus-kurchatovium standoff is a favourite case study in how international naming disputes in science get resolved.
Story

History & name

Soviet scientists at Dubna’s JINR struck first in 1964, reporting element 104 after slamming neon-22 into plutonium-242 and naming it kurchatovium after Igor Kurchatov, head of the Soviet atomic project. In 1969 Albert Ghiorso’s Berkeley team independently made other isotopes by bombarding californium-249 with carbon-12, proposing the name rutherfordium after Ernest Rutherford. Their quarrel over elements 104 to 106 — the famous “Transfermium Wars” — ended only in 1997, when IUPAC fixed the names used today: rutherfordium, dubnium and seaborgium.

Name originHonours Ernest Rutherford, father of nuclear physics and discoverer of the atomic nucleus.
Neighbours

Nearby elements

The elements that sit right beside this one on the table — often the closest chemical cousins.